Vapor Phase Dimethyl Carbonate Synthesis from Methyl Nitrite and Carbon Monoxide over Porous Lithium Aluminate Spinel Supported Palladium Catalyst.
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Gas-Phase Synthesis of Dimethyl Carbonate from Methanol and Carbon Dioxide Over Co1.5pw12o40 Keggin-Type Heteropolyanion
The reactivity of Co(1.5)PW(12)O(40) in the direct synthesis of dimethyl carbonate (DMC) from CO(2) and CH(3)OH was investigated. The synthesized catalyst has been characterized by means of FTIR, XRD, TG, and DTA and tested in gas phase under atmospheric pressure. The effects of the reaction temperature, time on stream, and methanol weight hourly space velocity (MWHSV) on the conversion and DMC...
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Most kinetic studies of methanol synthesis over Cu/ZnO catalysts have been carried out using mixtures of carbon monoxide and hydrogen. But in some cases (1) the synthesis gas has also contained carbon dioxide (2). Power rate laws as well as complicated rate expressions have been proposed over the years. The detailed kinetics of the surface processes is virtually unknown. With the exception, per...
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0921-8831/$ see front matter 2011 The Society of doi:10.1016/j.apt.2011.11.004 ⇑ Corresponding author. Address: School of Metallu ing, University of Tehran, P.O. Box 14395-1491, Tehran fax: +98 21 88006076. E-mail address: [email protected] (S. Sheibani). In this paper, the possibility of mechano-chemical synthesis, as a single step process for preparation of nanostructured nickel aluminate sp...
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Carbon Nanotubes Synthesis by Chemical Vapor Deposition of Methane over Zn – Fe Mixed Catalysts Supported on Alumina
Carbon nanotubes were synthesized over a series of Zn-containing Fe/alumina catalysts by chemical vapor deposition method at two reaction temperatures of 850 and 950 °C using methane as a carbon source. Catalysts were synthesized by keeping Fe concentration constant and varying Zn concentration to study the effects of Zn. The catalysts were characterized using X – ray powder diffraction and N2 ...
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1999
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1999.347